At pH 6.8 the half-life of phthtalic anhydride in water was prolonged to 61 seconds. SDS & Certificate of Analysis Phthalic anhydride is a common laboratory chemical, Pthalic anhydride has been shown to be esterified with primary alcohols at room temperature. Very toxic in contact with skin. Handle in accordance with good industrial hygiene and safety practice. endstream endobj 38 0 obj <> endobj 39 0 obj <> endobj 40 0 obj <>stream According to a classification scheme(2), this estimated Koc value suggests that phthalic anhydride is expected to have very high mobility in soil. The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Recommended Exposure Limit: 10 Hr Time-Weighted Avg: 6 mg/cu m (1 ppm). Hazard classification & labelling Hazard classification and labelling. Irritating to eyes, respiratory system and skin. Urine was also taken from a control group of 22 persons not occupational exposed to phthalic anhydride. P272 Contaminated work clothing should not be allowed out of the workplace. Phthalic anhydride is used in the preparation of primary amines. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). & Ind. chemBlink provides samples of SDS, Safety Data Sheets, for Phthalic anhydride, CAS 85-44-9 Solid irritates skin and eyes, causing coughing and sneezing. Purchase 85-44-9 Certified Reference Standards from AccuStandard. 74 0 obj <>stream § 321, and is therefore excluded from the definition of chemical substance4 as regulated by TSCA. Anhydrides. View information & documentation regarding Phthalic anhydride, including CAS, MSDS & more. Phthalic anhydride-containing products’ SDS list “food preservatives” as an identified use (InterAtlas 2016, Koppers 2018). A4; Not classifiable as a human carcinogen. SAFETY DATA SHEET: PHTHALIC ANHYDRIDE PHTHALIC ANHYDRIDE P392.10 INTEGRA Chemical Company 24 Hour Emergency Response: CHEMTREC 800-424-9300 (Outside USA 703-527-3887) 1216 6th Ave N Kent WA 98032 Phone: 253-479-7000 C8H4O3 148.12 P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Safety Data Sheet (SDS) Revision 1/ Review Date: 03/20/2020 1. 저희는 사용자에 맞게 사이트를 설정하여 사용자가 사이트를보다 원활하게 이용할 수 있도록 쿠키를 사용합니다. This colorless solid is an important industrial chemical, especially for the large–scale production of plasticizers for plastics. sds. CAS number: 66-44 9 EC number: 201.607-S ;�����(����������!i�m@Z���"��Qm����ҕmR���Bﲍ����b ��00����b��X�Q � �-� Combustible solidDust explosion possible if in powder or granular form, mixed with air.PHTHALIC ANHYDRIDE reacts exothermically with water. Polynt Group produces a great variety of anhydrides, but the most important ones are: Phthalic Anhydrides, Maleic Anhydride, Trimellitic Anhydride Refer for medical attention. Causes serious eye damage. It is slightly soluble in hot water, hydrolysing to PA, and is soluble in alcohol and carbon disulphide. Articles of Phthalic anhydride are included as well. Rinse and then wash skin with water and soap. Uses advised against Food, drug, pesticide or biocidal product use. 116088-82-5) SDS. Rinse and then wash skin with water and soap. To our knowledge the information is accurate and reliable, however, it is not guaranteed. Phthalic Anhydride SDS MSDS Sheet, Material Safety Data Sheet. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. SysKem Chemie: Avoid exposure - obtain special instructions before use.Provide appropriate exhaust ventilation at places where dust is formed. 500g; Glass bottle. Phthalic anhydride may be used as a reactant in the preparation of N-substituted phthalimides, poly(isothianaphthene) and methyl (S)-2-phthalimido-4-methylt hiobutanoate. 各製品詳細ページ,製品書類検索で分析チャートが検索できるようになりました。 (ご提供している分析チャートの種類は製品ごとに異なります。) tciメール最新号no.185を公開しました。 This Safety Data Sheet (SDS) is for guidance and is based upon information and tests believed to be reliable. Learn more about Phthalic anhydride. 82 (1), 126-133. Phthalic anhydride has a reported BCF of 4,053 in Oedogonium (alga) but did not bioconcentrate in Daphnia (water flea) or Physa (snail)(4). Half-upright position. Name of substance MALEIC ANHYDRIDE Identifiers CAS No 108-31-6 Molecular formula C4H2O3 Molar mass 98.06 g/mol Safety Data Sheet acc. H334 May cause allergy or asthma symptoms or … Phthalic anhydride is the organic compound with the formula:-C6H4(CO)2O. Availability. Do not discharge to sewer systems. H315 Causes skin irritation. Name of substance MALEIC ANHYDRIDE Identifiers CAS No 108-31-6 Molecular formula C4H2O3 Molar mass 98.06 g/mol Safety Data Sheet acc. Contact info . (ERG, 2016). We provide Phthalic Anhydride safety data sheets view and download at Echemi.com. Stable under recommended storage conditions. If not breathing give artificial respiration consult a physician. This is an organic compound obtained by the transformation of ortoxylene (derived from oil) through the use of catalysts (catalytic oxidation process). Personal precautions, protective equipment and emergency procedures: Use personal protective equipment. Contact with metals may evolve flammable hydrogen gas. Exclusion of liability : Information contained in this publication is accurate to the best of the knowledge and the belief of the company. For precautions see section 2.2. Mineralization of 33% of an initial concentration of 9 ppm phthalic anhyride incubated with activated sludge for 24 hrs was reported based on chemical oxygen demand(7). Phthalic anhydride, present at 100 mg/L, reached 85.2% of its theoretical BOD in 2 weeks using an activated sludge inoculum at 30 mg/L in the Japanese MITI test(3); it was noted that the phthalic anhydride had been hydrolyzed to phthalic acid(3). P332+P313 If skin irritation occurs: Get medical advice/attention. Material Name: PHTHALIC ANHYDRIDE - FLAKE SDS ID: 00227844 _____ Page 3 of 11 Issue date: 2020-01-23 Revision 3.0 Print date: 2020-01-23 Section 4 - FIRST AID MEASURES Inhalation If adverse effects occur, remove to uncontaminated area. Remove contact lenses, if present and easy to do. Eyes: Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. Phthalic anhydride itself is used as a monomer for synthetic resins such as glyptal, the alkyd resins, and the polyester resins. H318 Causes serious eye damage. P280 Wear protective gloves/protective clothing/eye protection/face protection. chemBlink provides samples of SDS, Safety Data Sheets, for Phthalic anhydride, CAS 85-44-9 Insect Repellents. TCC’s phthalic anhydride is a toxic, white crystalline compound used in the manufacture of phthaleins and other dyes, resins, plasticizers, and insecticides. Phthalic anhydride reacts violently with CuO at elevated temperatures [Park, Chang-Man, Richard J. Sheehan. Details of the supplier of the safety data sheet Emergency Telephone Number PubMed:[Effect of phthalic anhydride powder on the mucous membranes of the upper respiratory tract]. Separated from combustible substances, reducing agents, strong oxidants, strong bases, strong acids and food and feedstuffs. Wash hands before breaks and at the end of workday. 37 0 obj <> endobj Insect Repellents. Polynt Group produces a great variety of anhydrides, but the most important ones are: Phthalic Anhydrides, Maleic Anhydride, Trimellitic Anhydride Evacuate personnel to safe areas. Chemical formula: C8H403 Product type: Anhydride of organic aromatic d!carboxylic acid. Undergoes exothmeric nitration with fuming nitric acid-sulfuric acid and may give mixtures of the potentially explosive phthaloyl nitrates or nitrites or their nitro derivatives [Chem. Phthalic anhydride is an important chemical intermediate in the plastics industry from which are derived numerous phthalate esters that function as plasticizers in synthetic resins. May cause allergy or asthma symptoms or breathing difficulties if inhaled. John Wiley & Sons, Inc. 2005]. Refer for medical attention . CAS No. It reacts with strong oxidants and violently on heating with copper oxide or sodium nitrite, causing explosion hazard. View or download the Phthalic anhydride MSDS (Material Safety Data Sheet) or SDS for 800592 from MilliporeSigma. Phthalic anhydride hydrolyzes rapidly in the presence of water forming phthalic acid. It is used as a precursor to prepare anthraquinone, phthalein, rhodamine, phthalocyanine, fluorescein and xanthene dyes. It is used for the production of plasticizers and for different types of unsaturated polyester resins and alkyds. 0 Revision Date: May 16, 2014. Stepan Company: PHTHALIC ANHYDRIDE MOLTEN. 1.1 Product identifier. (6,8) Phthalic anhydride has an odor threshold of 0.053 parts per million (ppm). Phthalic Anhydride (PA) is used as the major ingredient in the manufacture of plasticizers, unsaturated polyester resin, paint and others. Phthalic anhydride is a white (lustrous needles) solid that is slightly soluble in water. Logistics services are available in the United States. Phthalic anhydride hydrolyzes rapidly in water with a half-life of about 25 minutes or less at 25\u00b0C(1,5) which suggests that bioconcentration in fish may not be an important fate process(SRC). 99MZzr����,i��92/�-����1#'��'/H��#���0A)�F~߼Ɇ��n�m9����U}d9-�Ɏ1ub`$��3��~��}_�e�i���u�Q�ia�LJ�7�F؉��ub`\ݤ릞��ɮߎ�I�o��\�a�O�/n��3N�Y�5Y� Y�%��o��pxQ��l����%�\��O!��?���}�bS������.W��dV�jqI���ɷm|,hVo;�����,nZ�uȆ���X-�->���عzJ�l�*;�*��⢾��I!�cJ��1M�Q��V�~�4��n��-]�'�U����|Y�.��. CAS 85-44-9, pH 2 (6 g/l, H₂O, 20 °C). Wear self-contained breathing apparatus for firefighting if necessary. Most vapors are heavier than air. Other uses include dyes, pharmaceuticals, insecticides, and as a laboratory reagent. 115080-Phthalic anhydride Version: 2 Revision date: 20/04/2016 Page 1 of 9 Print date: 20/04/2016 -Continued on next page.-SECTION 1: IDENTIFICATION OF THE SUBSTANCE AND OF THE COMPANY/UNDERTAKING. Phthalic anhydride vapour, fume or dust is a primary irritant. Section 3 - Hazards Identification Risk advice to man and the environment Toxic if swallowed. Products / Product Information / Phthalic Anhydride. Phthalic anhydride-containing products’ SDS list “food preservatives” as an identified use (InterAtlas 2016, Koppers 2018). Phthalic anhydride is also used as a precursor of anthraquinone, phthalein, rhodamine, phthalocyanine, fluorescein, and xanthene dyes. Phthalic anhydride is a chemical intermediate that reacts readily and produces a broad range of products that process easily and give a wide range of performance characteristics at a low cost. Shop a large selection of Oxacyclic compounds products and learn more about Phthalic anhydride, ACS reagent, ACROS Organics. P302+P352 IF ON SKIN: Wash with plenty of water/... P321 Specific treatment (see ... on this label). They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Chemsrc provides Phthalic anhydride(CAS#:85-44-9) MSDS, density, melting point, boiling point, structure, formula, molecular weight etc. Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours). Consult a physician. Using OECD Method 301D (closed bottle test) and a domestic sewage inoculum, phthalic anhydride reached 71% of theoretical BOD after 30 days(1). SDS / MSDS Product Name: PHTHALIC ANHYDRIDE Revision Date : 03.06.2019 Page 2 of 6 Hazard statement(s): H302 : Harmful if swallowed H315 : Causes skin irritation H318 : Causes serious eye damage H334 : May cause allergy or asthma symptoms or breathing difficulties if inhaled H317 : May cause an allergic skin reaction endstream endobj startxref Chemical Product and Company Identification Product Name: Phthalic Anhydride Distributed By: HB Chemical 1665 Enterprise Parkway Twinsburg Oh 44087 Phone - 330-920-8023 MSDS Prepared By (w Suppliers Input): HB Chemical Chemical Name / Family: Not available Other reactions with phthalic anhydride yield phenolphthalein, benzoic acid, phthalylsulfathiazole (an intestinal antimicrobial agent), and orthophthalic acid. Substance will react with water (some violently) releasing flammable, toxic or corrosive gases and runoff. Hazard statement(s ) H302 Harmful if swallowed. Gloves must be inspected prior to use. Refer for medical attention. It is the anhydride of phthalic acid. Half-life for phthalic anhydride was 30.5 seconds at pH 7.24. This white solid is an important industrial chemical, especially for the large-scale production of plasticizers for plastics. Phthalic Anhydride. Phthalic anhydride is an important chemical intermediate in the plastics industry from which are derived numerous phthalate esters that function as plasticizers in synthetic resins. Sweep spilled substance into covered containers. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. Airborne phthalic anhydride levels ranged from 0.03 to 10.5 mg/cu m (mean value, MMAD not stated), determined from personal air samples from the worker breathing zone. Handle with gloves. To request copies of either please click on the Request Product Information button above and complete the form. Fresh air, rest. Phthalic anhydride is a versatile intermediate in organic chemistry, primarily used in the production of general purpose plasticizers, unsaturated polyesters (UPRs), alkyd resins and polyols (APPs). Phthalic anhydride is available in both flake and liquid molten form; Knowledgeable, experienced technical assistance. No studies regarding reproductive or developmental effects in humans were available. Phthalic Anhydride. Phthalic anhydride itself is used as a monomer for synthetic resins such as glyptal, the alkyd resins, and the polyester resins. SDS & Certificate of Analysis Phthalic anhydride is a common laboratory chemical, Pthalic anhydride has been shown to be esterified with primary alcohols at room temperature. Phthalic Anhydride CAS No 85-44-9 MATERIAL SAFETY DATA SHEET SDS/MSDS. 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Releasing flammable, toxic or corrosive gases and runoff be used commercially sanitary landfill anhydride itself is used for large–scale... 30.5 seconds at pH 7.24 MSDS & more is formed to drink and amount the. View and download at Echemi.com! carboxylic acid acids and food and feedstuffs recommended exposure:... Rapidly in the plastics industry as well as headache and dizziness can occur were... Anhydride itself is used for the production of plasticizers for plastics plasticizers for plastics learn.