Copyright © 2021 by John Wiley & Sons, Inc., or related companies. Adipic acid has also been incorporated into controlled-release formulation … Adipic acid CAS 124-04-9 WIKI information includes physical and chemical properties, USES, security data, NMR spectroscopy, computational chemical data and more. Adipic Acid or Hexanedioic acid has a very simple IR Spectrum. 13C Nuclear Magnetic Resonance (NMR) Chemical Shifts of Adipic acid, dimethyl ester with properties. Starting … The yield of adipic acid was 30% with melting point 149-151 °C. It occurs relatively rarely in nature. SpectraBase Spectrum ID=1d01jpzhAj7. Adipic acid (AA) is a 6-carbon diacid and a building block in the synthesis of Nylon-66. A Repository for Data from NMR Spectroscopy on Proteins, Peptides, Nucleic Acids, and other Biomolecules: Member of: Home; About BMRB. It derives from an adipic acid . Adipic Acid × × Purity: >99.0%(GC ... 152.0 to 155.0 °C: Solubility in Methanol: almost transparency: Properties (reference) Melting Point: 153 °C: Solubility in water: Slightly soluble: Degree of solubility in water : 22 g/l 20 °C: Solubility (very soluble in) Alcohol: Solubility (soluble in) Acetone : Safety & Regulations. Food acidulant Adipic acid is a compound of the class of carboxylic acids that is derived from oxidation of various fats. Adipic acid is the organic compound with the formula (CH 2) 4 (COOH) 2. Adipic acid or hexanedioic acid is the organic compound with the formula (CH2)4(COOH)2. A Repository for Data from NMR Spectroscopy on Proteins, Peptides, Nucleic Acids, and other Biomolecules: Member of: Home; About BMRB. It is also used in some calcium carbonate antacids to make them tart. Compound Adipic acidwith free spectra: 32 NMR, 13 FTIR, 4 Raman, and 11 MS. CERT OF ANALYSIS. The yield of adipic acid was 30% with melting point 149-151 °C. It is mildly toxic, with LD50 of 3600 mg/kg for oral ingestion by rats. Carboxylic acids: Co, C-o. Adipic Acid Production Reactions A –80 ˚C LB:glycerol stock of E. coli BL21(DE3), E. coli Lemo21(DE3), or E. coli BL21(DE3) ΔiscR , harbouring the pAA or pAA’, and pGro7, pKJE7 or pTf16 plasmids was inoculated into 10 mL of LB Adipic acid Compound with free spectra: 5 NMR, 8 FTIR, and 3 Raman. sadtler nmr number: 4406m: solvent: dmso-d6: synonyms: hexanedioic acid 1,4-butanedicarboxylic acid adipinic acid: use: intermediate in lubricating oil additives; used to produce artificial resins, nylons, and plastics; replacement for tartaric acid, cream of tartar and phosphates in baking powders; general-purpose food additive Adipic acid, diglycidyl ether of bisphenol A, m-chloroperoxy-benzoic acid <77%, sodium hydroxide, epichlorohydrin, allyl alcohol, benzyl trimethylammonium chloride, 0.1 N perchloric acid in acetic acid, acetic acid, crystal violet, and benzyl triethylammonium chloride were purchased and used as received from Sigma-Aldrich. 1 H and 13 C NMR spectra of polyesters were obtained with a Bruker 400 MHz. ADIPINIC ACID, INTERMEDIATE IN LUBRICATING OIL ADDITIVES; USED TO PRODUCE ARTIFICIAL RESINS, NYLONS, AND PLASTICS; REPLACEMENT FOR TARTARIC ACID, CREAM OF TARTAR AND PHOSPHATES IN BAKING POWDERS; GENERAL-PURPOSE FOOD ADDITIVE. SDS; ADIPIC ACID (5-INDANYLMETHYLENE)-HYDRAZIDE. Get the latest public health information from CDC: https://www.coronavirus.gov. KSC489S5P. 6-ethoxy-6-keto-hexanoic acid. The oxidation temperature at 100 °C gave the highest adipic acid 48% was obtained. 3 System Maintenance Alert: Due to planned maintenance of our internal systems, web functionality including order placement, price and availability checks and SDS display will not be available for Asia and several European countries from Saturday, November 7th at 2:30 CET until Sunday, November 8th at 7:00 AM CET. 1D NMR Spectrum 1374 - Adipic acid (HMDB0000448) 1D NMR Spectrum 2205 - Adipic acid (HMDB0000448) 1D NMR Spectrum 2899 - Adipic acid (HMDB0000448) Human Metabolome Database (HMDB) 1D NMR Spectra : NMRShiftDB Link. NMRShiftDB. eCl@ss 39021711 . Adipic Acid × × Purity: >99.0%(GC ... 152.0 to 155.0 °C: Solubility in Methanol: almost transparency: Properties (reference) Melting Point: 153 °C: Solubility in water: Slightly soluble: Degree of solubility in water : 22 g/l 20 °C: Solubility (very soluble in) Alcohol: Solubility (soluble in) Acetone : Safety & Regulations. It has a tart taste and is also used as an additive and gelling agent in jello or gelatins. Synthesis of adipic acid from glucaric (aldaric 32) acid over homogeneous MeReO 3 in alcohol with para‐toluenesulfonic acid (PTSA) or Amberlyst 15 was presented by Hong et al. 153 °C TCI A0161: 151-155 °C Alfa Aesar: 151-154 °C Indofine [15-0600] , [15-0600] : 152 °C OU Chemical Safety Data (No longer updated) More details: 150-154 °C Merck Millipore 2849, 818650: 152 °C Jean-Claude Bradley Open Melting Point Dataset 15578: 153.2 °C Jean-Claude Bradley Open Melting Point Dataset 22499: 153 °C Jean-Claude Bradley Open Melting Point Dataset 13894, 6339 33 The process consists of (i) dehydroxylation of the aldaric ester, (ii) hydrogenation of the ensuing muconic ester, and (iii) the ensuing adipic ester hydrolysis. Adipic acid monoethyl ester, 97%. d t-BuOOH was used as oxidant. Hexane dioic acid monoethyl ester. The polyesterification of adipic acid, AA, with trimethylolpropane, TMP, was monitored by 1H and 13C NMR as a function of reaction time, in tetrahydrofuran as solvent. Copyright © 2017 ChemicalBook All rights reserved. Adipinsäure wird durch Oxidation von Cyclohexen oder Cyclohexanol mit Kaliumpermanganat oder Salpetersäure gewonnen, in der Natur kommt sie in nennenswerten Mengen in der Zuckerrübe und in … Eigenschaften. Search results for adipic acid at Sigma-Aldrich. Shanghai Aladdin Bio-Chem Technology Co.,LTD. The polyesterification of adipic acid, AA, with trimethylolpropane, TMP, was monitored by 1H and 13C NMR as a function of reaction time, in tetrahydrofuran as solvent. The oxidation temperature at 100 °C gave the highest adipic acid 48% was obtained. View entire compound with free spectra: 32 NMR, 13 FTIR, 4 Raman, and 11 MS, InChI=1S/C6H10O4/c7-5(8)3-1-2-4-6(9)10/h1-4H2,(H,7,8)(H,9,10), The Matheson Company, Inc., East Rutherford, New Jersey. COVID-19 is an emerging, rapidly evolving situation. Adipic acid 99% Synonym: ADI-PURE ® LGA adipic acid, ADI-PURE ® high purity adipic acid, Hexanedioic acid CAS Number 124-04-9. STRUCTURE SEARCH. Download Image. First at 1690 cm-1 for the CO stretch and other at 3100 cm-1 for OH stretch. CTK3I9957. The structure and molecular weight of the hyperbranched polyesterification of adipic acid and glycerol were characterized by 13 C NMR spectroscopy and size-exclusion chromatography as a function of reaction time and reaction stoichiometry. Citing BMRB; News; Mailing list; BMRB Description ; BMRB Staff; Mission statement; Search archive. It is a conjugate acid of a 2-hydroxyadipate(2-). John Wiley & Sons, Inc. SpectraBase; SpectraBase Compound ID=BnVRPXAZUid SpectraBase Spectrum ID=KZgHNmQwES8 The glycerol substitution patterns and the extent of reaction of both glycerol and adipic acid were determined by NMR. Chengdu XiYa Chemical Technology Co., Ltd. Dimethyl 1,4-cyclohexanedicarboxylate (94-60-0)MS, www.chemicalbook.com/ShowSupplierProductsList717200/0.htm, https://www.tcichemicals.com/zh/cn/index.html. *Please select more than one item to compare Synthesis of adipic acid from glucaric (aldaric 32) acid over homogeneous MeReO 3 in alcohol with para‐toluenesulfonic acid (PTSA) or Amberlyst 15 was presented by Hong et al. Search Archive; Query Grid Interface; FASTA search; New Entries; Entries on Hold; Withdrawn Entries; NMR Time-domain Data; NMR Restraints from PDB MR … Solid State 13 C NMR Spectra Of (a) Adipic Acid And Adipic Acid, Butanediol, P,p-diphenylmethane Diisocyanate 124-04-9 - Guidechem [Full Text] Hyaluronic Acid-nimesulide Conjugates As. Use numbers (1, 2, 3, etc.) NSC8877. Get more help from Chegg. EC Number 204-673-3. The oxidation temperature at 100 °C gave the highest adipic acid 48% was obtained. Search results for Adipic acid at Sigma-Aldrich. 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